(η6-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536806025256

(η⁶-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate

Reinout Meijboom, Alfred Muller, Andreas Roodt

University of The Free State

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [RuCl₂(C₂₇H₃₃O ₃P)(C₆H₆)]·CH₂Cl ₂, the Ru-P bond distance is 2.2790 (4) Å, and the Ru-Cl bond distances are 2.4052 (4) and 2.4046 (4) Å. The title compound is the first reported structure containing tris(2isopropylphenyl)phosphite as a ligand. The effective cone angle (θ_E) for the tris(2-isopropylphenyl) phosphite was calculated to be 160°.

Original language	English
Pages (from-to)	m1866-m1868
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	8
DOIs	https://doi.org/10.1107/S1600536806025256
Publication status	Published - Aug 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(η6-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate",

abstract = "In the title compound, [RuCl2(C27H33O 3P)(C6H6)]·CH2Cl 2, the Ru-P bond distance is 2.2790 (4) {\AA}, and the Ru-Cl bond distances are 2.4052 (4) and 2.4046 (4) {\AA}. The title compound is the first reported structure containing tris(2isopropylphenyl)phosphite as a ligand. The effective cone angle (θE) for the tris(2-isopropylphenyl) phosphite was calculated to be 160°.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2006",

month = aug,

doi = "10.1107/S1600536806025256",

language = "English",

volume = "62",

pages = "m1866--m1868",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - (η6-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2006/8

Y1 - 2006/8

N2 - In the title compound, [RuCl2(C27H33O 3P)(C6H6)]·CH2Cl 2, the Ru-P bond distance is 2.2790 (4) Å, and the Ru-Cl bond distances are 2.4052 (4) and 2.4046 (4) Å. The title compound is the first reported structure containing tris(2isopropylphenyl)phosphite as a ligand. The effective cone angle (θE) for the tris(2-isopropylphenyl) phosphite was calculated to be 160°.

AB - In the title compound, [RuCl2(C27H33O 3P)(C6H6)]·CH2Cl 2, the Ru-P bond distance is 2.2790 (4) Å, and the Ru-Cl bond distances are 2.4052 (4) and 2.4046 (4) Å. The title compound is the first reported structure containing tris(2isopropylphenyl)phosphite as a ligand. The effective cone angle (θE) for the tris(2-isopropylphenyl) phosphite was calculated to be 160°.

UR - http://www.scopus.com/inward/record.url?scp=33747178391&partnerID=8YFLogxK

U2 - 10.1107/S1600536806025256

DO - 10.1107/S1600536806025256

M3 - Article

AN - SCOPUS:33747178391

SN - 1600-5368

VL - 62

SP - m1866-m1868

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

(η⁶-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate

Abstract

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