(η6-benzene)(benzyldiphenylphosphane)- dichloridoruthenium(II)

Alfred Muller; Wade L. Davis

doi:10.1107/S1600536812037154

(η⁶-benzene)(benzyldiphenylphosphane)- dichloridoruthenium(II)

Alfred Muller, Wade L. Davis

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [RuCl₂(C6H₆)(C19H1 ₇P)], the Ru^II atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(η⁶-benzene) = 1.6894 (11) Å, Ru-P = 2.3466 (6), Ru-Cl(avg.) = 2.4127 (7) Å; Cl-Ru-Cl = 88.07 (2) and Cl-Ru-P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C-H··· Cl and C-H···π interactions are observed.

Original language	English
Pages (from-to)	m1232-m1233
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	10
DOIs	https://doi.org/10.1107/S1600536812037154
Publication status	Published - Oct 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(η6-benzene)(benzyldiphenylphosphane)- dichloridoruthenium(II)",

abstract = "In the title compound, [RuCl2(C6H6)(C19H1 7P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(η6-benzene) = 1.6894 (11) {\AA}, Ru-P = 2.3466 (6), Ru-Cl(avg.) = 2.4127 (7) {\AA}; Cl-Ru-Cl = 88.07 (2) and Cl-Ru-P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C-H··· Cl and C-H···π interactions are observed.",

author = "Alfred Muller and Davis, {Wade L.}",

year = "2012",

month = oct,

doi = "10.1107/S1600536812037154",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - (η6-benzene)(benzyldiphenylphosphane)- dichloridoruthenium(II)

AU - Muller, Alfred

AU - Davis, Wade L.

PY - 2012/10

Y1 - 2012/10

N2 - In the title compound, [RuCl2(C6H6)(C19H1 7P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(η6-benzene) = 1.6894 (11) Å, Ru-P = 2.3466 (6), Ru-Cl(avg.) = 2.4127 (7) Å; Cl-Ru-Cl = 88.07 (2) and Cl-Ru-P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C-H··· Cl and C-H···π interactions are observed.

AB - In the title compound, [RuCl2(C6H6)(C19H1 7P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(η6-benzene) = 1.6894 (11) Å, Ru-P = 2.3466 (6), Ru-Cl(avg.) = 2.4127 (7) Å; Cl-Ru-Cl = 88.07 (2) and Cl-Ru-P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C-H··· Cl and C-H···π interactions are observed.

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U2 - 10.1107/S1600536812037154

DO - 10.1107/S1600536812037154

M3 - Article

AN - SCOPUS:84867191764

SN - 1600-5368

VL - 68

SP - m1232-m1233

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

(η⁶-benzene)(benzyldiphenylphosphane)- dichloridoruthenium(II)

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