η3-diphosphavinylcarbene: A P2 lthe dötz Intermediate

Halil Aktas; J. Chris Slootweg; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1002/anie.200805037

η³-diphosphavinylcarbene: A P₂ lthe dötz Intermediate

Halil Aktas, J. Chris Slootweg, Andreas W. Ehlers, Martin Lutz, Anthony L. Spek, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Do the twist: The reaction of in situ generated phosphinidenes with phosphaalkynes is a facile route to the new metal-coordinated η³-diphosphavinylcarbene 1, which shows facile ligand-exchange reactions and undergoes an unprecedented rearrangement that involves phosphinidene complex 2 and η³-phosphaalkenylphosphinidene complex 3, the 1,3 isomer of 1.

Original language	English
Pages (from-to)	3108-3111
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	17
DOIs	https://doi.org/10.1002/anie.200805037
Publication status	Published - 14 Apr 2009
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200805037

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title = "η3-diphosphavinylcarbene: A P2 lthe d{\"o}tz Intermediate",

abstract = "Do the twist: The reaction of in situ generated phosphinidenes with phosphaalkynes is a facile route to the new metal-coordinated η3-diphosphavinylcarbene 1, which shows facile ligand-exchange reactions and undergoes an unprecedented rearrangement that involves phosphinidene complex 2 and η3-phosphaalkenylphosphinidene complex 3, the 1,3 isomer of 1.",

author = "Halil Aktas and Slootweg, {J. Chris} and Ehlers, {Andreas W.} and Martin Lutz and Spek, {Anthony L.} and Koop Lammertsma",

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T2 - A P2 lthe dötz Intermediate

AU - Aktas, Halil

AU - Slootweg, J. Chris

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

PY - 2009/4/14

Y1 - 2009/4/14

N2 - Do the twist: The reaction of in situ generated phosphinidenes with phosphaalkynes is a facile route to the new metal-coordinated η3-diphosphavinylcarbene 1, which shows facile ligand-exchange reactions and undergoes an unprecedented rearrangement that involves phosphinidene complex 2 and η3-phosphaalkenylphosphinidene complex 3, the 1,3 isomer of 1.

AB - Do the twist: The reaction of in situ generated phosphinidenes with phosphaalkynes is a facile route to the new metal-coordinated η3-diphosphavinylcarbene 1, which shows facile ligand-exchange reactions and undergoes an unprecedented rearrangement that involves phosphinidene complex 2 and η3-phosphaalkenylphosphinidene complex 3, the 1,3 isomer of 1.

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U2 - 10.1002/anie.200805037

DO - 10.1002/anie.200805037

M3 - Article

C2 - 19072973

AN - SCOPUS:65349170090

SN - 1433-7851

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JF - Angewandte Chemie - International Edition

IS - 17

ER -

η³-diphosphavinylcarbene: A P₂ lthe dötz Intermediate

Abstract

ASJC Scopus subject areas

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